Search for a command to run...
We report the x-ray absorption studies on O K, Fe L3,2, Ni L3,2, and Pr M5,4 edges in PrFe1−xNixO3 along with their structural, electrical transport, and magnetization characterizations. All the samples are in single phase having orthorhombic structure with space group Pnma for x⩽0.4. Ni doping at Fe site brings the system in the conducting regime, resistivity decreases from GΩcmto260mΩcm at room temperature, and the magnetic ordering is stabilized. The temperature dependent resistivity follows the semiconducting behavior and fits well with Greaves’ variable range hopping model. The gap parameter is reduced from 2to0.118eV. The materials are in weak ferromagnetic state and magnetization is gradually decreasing with the enhancement of Ni substitution, whereas magnetic anisotropy is reduced substantially. A new feature about 2.0eV lower than the pre-edge of PrFeO3 in O K edge is observed with Ni substitution at Fe site due to the 3d contraction effect and is growing with the increase of Ni substitution. From 2p edges (L3,2 edges) of Fe and Ni, it is confirmed that both are in trivalent state and Ni is in mixed spin state with 3d7 (t2g5,eg2 and t2g6,eg1) configuration in ground state. The trivalent state of Pr is confirmed by x-ray absorption spectroscopy of Pr at M5,4 edges. These observations have been explained on the basis of charge carrier doping in PrFeO3 with the Ni substitution. The disorder induced localization is found to control the conductivity and magnetism in the present materials. The controlled doping of carriers in semiconducting regime and ferromagnetism propose these materials as a promising candidate for the spintronic applications.