Observation of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msup><mml:mi>B</mml:mi><mml:mn>0</mml:mn></mml:msup><mml:mo>→</mml:mo><mml:mi>p</mml:mi><mml:mover accent="true"><mml:mi>Λ</mml:mi><mml:mo>¯</mml:mo></mml:mover><mml:msup><mml:mi>π</mml:mi><mml:mo>−</mml:mo></mml:msup></mml:math>

We report the first observation of the charmless hyperonic B decay, B0-->pLambda(pi)(-), using a 78 fb(-1) data sample recorded on the Upsilon(4S) resonance with the Belle detector at KEKB. The measured branching fraction is B(B0-->pLambda(pi)(-))=(3.97(+1.00)(-0.80)+/-0.56)x10(-6). Searches for B0-->pLambda(K)- and pSigma(0)pi(-) yield no significant signals and we set 90% confidence-level upper limits of B(B0-->pLambda(K)-)<8.2x10(-7) and B(B0-->pSigma(0)pi(-))<3.8x10(-6).