Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends

2015969 citationsJournal Article

Authors

Jakob Kibsgaard · Interface (United States)

Charlie Tsai · SLAC National Accelerator Laboratory

Karen Chan · Interface (United States)

Jesse D. Benck · Stanford Medicine

Jens K. Nørskov · SLAC National Accelerator Laboratory

Frank Abild‐Pedersen · Interface (United States)

Thomas F. Jaramillo

Abstract

A volcano relationship exists between hydrogen evolution activities and hydrogen adsorption free energies for transition metal phosphides. We further predict and confirm that Fe<sub>0.5</sub>Co<sub>0.5</sub>P exhibits the highest activity.

Topics & Keywords

Electrocatalysts for Energy Conversion Catalysis and Hydrodesulfurization Studies Metalloenzymes and iron-sulfur proteins

Publication Details

Published in: Energy & Environmental Science

Volume 8, Issue 10, pp. 3022-3029

DOI: 10.1039/c5ee02179k

Field-Weighted Citation Impact: 27.60

Command Palette

Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends

Authors

Abstract

Topics & Keywords

Publication Details