FLUORIDE-INDUCED 1,2-ELIMINATION OF <i>O</i>-TRIMETHYLSILYLPHENYL TRIFLATE TO BENZYNE UNDER MILD CONDITIONS

1983921 citationsJournal Article

Authors

Abstract

Abstract Fluoride-induced 1,2-elimination of o-trimethylsilylphenyl triflate provided a convenient route to benzyne under mild conditions where detriflation from an intermediary aryl anion appeared to occur in preference to protonation even in the presence of alcohols.

Topics & Keywords

Cyclization and Aryne Chemistry Chemical Reactions and Mechanisms Fluorine in Organic Chemistry

UN Sustainable Development Goals

Clean water and sanitation

Publication Details

Published in: Chemistry Letters

Volume 12, Issue 8, pp. 1211-1214

DOI: 10.1246/cl.1983.1211

Field-Weighted Citation Impact: 2.88