A one-pot strategy to synthesize β-ketophosphonates: silver/copper catalyzed direct oxyphosphorylation of alkynes with H-phosphonates and oxygen in the air

201599 citationsJournal Article

Authors

Xin Chen · Zhengzhou University

Xu Li · Zhengzhou University

Xiaolan Chen · Henan University of Technology

Xiaolan Chen · Zhengzhou University

Lingbo Qu · Zhengzhou University

Jianyu Chen · Zhengzhou University

Abstract

A highly efficient one-pot strategy has been developed for the synthesis of β-ketophosphonates directly from alkynes and dialkyl H-phosphonates in the presence of widely available AgNO3/CuSO4 and K2S2O8 at room temperature under open-air conditions.

Topics & Keywords

Sulfur-Based Synthesis Techniques Catalytic C–H Functionalization Methods Organophosphorus compounds synthesis

Publication Details

Published in: Chemical Communications

Volume 51, Issue 18, pp. 3846-3849

DOI: 10.1039/c4cc10312b

Field-Weighted Citation Impact: 8.92

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A one-pot strategy to synthesize β-ketophosphonates: silver/copper catalyzed direct oxyphosphorylation of alkynes with H-phosphonates and oxygen in the air

Authors

Abstract

Topics & Keywords

Publication Details