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Estimates of the radial electric field Er at the plasma periphery are obtained by measuring the drift velocities of low-Z impurity ions (He II, B IV, C III). The drift velocities are determined from the differential Doppler shift of visible line emission observed along opposite viewing directions. The principle of the measurement, including contributions from the diamagnetic drift, as well as radial gradients in the excitation rate and the effect of integrating along the line of sight are discussed in detail. The measured line of sight averaged drift velocities can be strongly influenced by the location and shape of the Er profile, especially if, as measured on other tokamaks, it is localized to a narrow region just within the separatrix. Values of Er estimated by assuming a constant radial profile underestimate maximum local values. During the H*-phase, however, high line of sight averaged perpendicular drift velocities of the B IV ions of a least 15 km/s in the electron diamagnetic drift direction are observed. From this, the presence of a strong negative radial electric field of at least 25 kV/m in the plasma edge region is inferred. Values of the B IV ion poloidal drift velocity calculated from an appropriate neoclassical theory are in the same direction as those measured. However, the calculated line of sight averaged values are much smaller than the measured ones. This reinforces the conclusion that a strong negative radial electric field is present just within the separatrix during the H-mode