Extraordinary Atomic Mobility of Au{111} at 80 Kelvin: Effect of Styrene Adsorption

We describe how the presence of styrene, a weakly adsorbed molecule, dramatically restructures the Au{111} surface at temperatures as low as 80 K. The restructuring manifests itself both in mobility of step-edge atoms, as well as changes in the position of the herringbone reconstruction over time. These effects are explained in terms of the preferential adsorption sites of styrene allowing it to assist in atom detachment from step edges, as well as lowering of the energetic barrier for movement of the herringbone reconstruction. This work has important consequences for studies in which Au is used as a support for or as an electrical contact to molecules.