The two metallicity groups of the globular cluster M 22: a chemical perspective

We present a detailed chemical composition analysis of 35 red giant stars in the globular cluster M 22. High resolution spectra for this study were obtained at five observatories, and analyzed in a uniform manner. We have determined abundances of representative light proton-capture, α, Fe-peak and neutron-capture element groups. Our aim is to better understand the peculiar chemical enrichment history of this cluster, in which two stellar groups are characterized by a different content in iron, neutron capture elements Y, Zr and Ba, and α element Ca. The principal results of this study are: (i) substantial star-to-star metallicity scatter (− 2.0 ≲ [Fe/H] ≲ −1.6); (ii) enhancement of s-process/r-process neutron-capture abundance ratios in a fraction of giants, positively correlated with metallicity; (iii) sharp separation between the s-process-rich and s-process-poor groups by [La/Eu] ratio; (iv) possible increase of [Cu/Fe] ratios with increasing [Fe/H], suggesting that this element also has a significant s-process component; and (v)presence of Na-O and C-N anticorrelations in both the stellar groups.