Dependence of giant magnetoresistance on oxygen stoichiometry and magnetization in polycrystalline<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">La</mml:mi></mml:mrow><mml:mrow><mml:mn>0.67</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow><mml:mrow><mml:mn>0.33</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">MnO</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant="italic">z</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>

We have studied resistivity, magnetization, and magnetoresistance in polycrystalline ${\mathrm{La}}_{0.67}$${\mathrm{Ba}}_{0.33}$${\mathrm{MnO}}_{\mathit{z}}$ by reducing the oxygen stoichiometry from z=2.99 to 2.80. As the oxygen content decreases, the resistivity of ${\mathrm{La}}_{0.67}$${\mathrm{Ba}}_{0.33}$ ${\mathrm{MnO}}_{\mathit{z}}$ increases and the magnetic transition temperature shifts to lower temperature. A large magnetoresistance effect was observed over a wide temperature range for all samples except the insulating z=2.80 sample. The similarity between our results on oxygen-deficient polycrystalline ${\mathrm{La}}_{0.67}$ ${\mathrm{Ba}}_{0.33}$${\mathrm{MnO}}_{\mathit{z}}$ and films previously reported to have a very large intrinsic magnetoresistance is discussed. At low temperature the magnetoresistance was observed to be strongly dependent on the magnetization. A possible mechanism for this effect is discussed.