Silver‐Tellurolate Polynuclear Complexes: From Isolated Cluster Units to Extended Polymer Chains

199757 citationsJournal Article

Authors

John F. Corrigan · Karlsruhe Institute of Technology

Dieter Fenske · Karlsruhe Institute of Technology

William P. Power · University of Waterloo

Abstract

In the presence of tertiary phosphanes, AgCl reacts readily with the reagent Te(Ph)SiMe3 to yield silver-tellurolate polynuclear complexes. In the case of PMe3, the polymer [Ag10(μ3-TePh)10(PMe3)2]∞ (shown below) is formed, in which the TePh ligands serve as both inter- and intracluster bridges.

Topics & Keywords

Organometallic Compounds Synthesis and Characterization Synthesis and characterization of novel inorganic/organometallic compounds Organometallic Complex Synthesis and Catalysis

UN Sustainable Development Goals

Clean water and sanitation

Publication Details

Published in: Angewandte Chemie International Edition in English

Volume 36, Issue 11, pp. 1176-1179

DOI: 10.1002/anie.199711761

Field-Weighted Citation Impact: 4.24