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Molecular dynamics simulations of monolayers of nonionic, poly(ethylene oxide) based surfactants are reported. Specifically, alcohol ethoxylates and alkylphenol ethoxylates are compared in terms of the varying architecture of the molecules for the development of a structure-behavior relationship. Interfacial density profiles are used to assess the structure of the monolayers, the penetration of water and oil into the monolayers, and the solvation of the hydrophiles and hydrophobes. Chain conformational descriptors are used to examine the molecular structure of the surfactants. The simulations revealed that monolayers of alcohol ethoxylates are considerably more diffuse than their alkylphenol counterparts, with the packing being governed by the size of the hydrophile. With the exception of the branched alcohol ethoxylate, the intermixing of the bulk phases within monolayers of alcohol ethoxylates increases with increasing hydrophile length. By comparison, the packing of alkylphenol ethoxylates within the monolayer is governed by the aromatic nucleus in the molecule. No specific interaction is observed between the aromatic rings of neighboring molecules. Monolayers of alkylphenol ethoxylates are more compact than their alcohol counterparts, resulting in more effective separation of the bulk water and oil phases.