Imine hydrogenation by alkylaluminum catalysts

201357 citationsJournal Article

Authors

Jillian A. Hatnean · University of Toronto

Douglas W. Stephan · University of Toronto

Abstract

Di-isobutylaluminum hydride and tri-iso-butylaluminum (DIBAL 1, TIBAL 2) are shown to be efficient hydrogenation catalysts for a variety of imines at 100 °C and 100 atm of H2, operating via a hydroalumination/hydrogenolysis mechanism.

Topics & Keywords

Asymmetric Hydrogenation and Catalysis Chemical Synthesis and Analysis Catalysis for Biomass Conversion

Publication Details

Published in: Chemical Communications

Volume 50, Issue 3, pp. 301-303

DOI: 10.1039/c3cc47889k

Field-Weighted Citation Impact: 1.33

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Imine hydrogenation by alkylaluminum catalysts

Authors

Abstract

Topics & Keywords

Publication Details