Agostic interactions in transition metal compounds

20071,079 citationsJournal Articlegreen Open Access

Authors

Maurice Brookhart · University of North Carolina at Chapel Hill

Malcolm L. H. Green · University of Oxford

Abstract

The impact of agostic interactions (i.e., 3-center-2-electron M-H-C bonds) on the structures and reactivity of organotransition metal compounds is reviewed.

Topics & Keywords

Organometallic Complex Synthesis and Catalysis Synthesis and characterization of novel inorganic/organometallic compounds Coordination Chemistry and Organometallics

Publication Details

Published in: Proceedings of the National Academy of Sciences

Volume 104, Issue 17, pp. 6908-6914

DOI: 10.1073/pnas.0610747104

Field-Weighted Citation Impact: 28.31

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Agostic interactions in transition metal compounds

Authors

Abstract

Topics & Keywords

Publication Details