Remarkable influence of secondary catalyst site on enantioselective desymmetrization of cyclopentenedione

2014105 citationsJournal Article

Authors

Madhu Sudan Manna · Bangalore University

Santanu Mukherjee · Indian Institute of Science Bangalore

Abstract

An efficient, robust and highly enantioselective catalytic desymmetrization of 2,2-disubstituted cyclopentene-1,3-diones is developed <italic>via</italic> direct vinylogous nucleophilic addition of deconjugated butenolides.

Topics & Keywords

Asymmetric Synthesis and Catalysis Synthetic Organic Chemistry Methods Oxidative Organic Chemistry Reactions

Publication Details

Published in: Chemical Science

Volume 5, Issue 4, pp. 1627-1633

DOI: 10.1039/c3sc53102c

Field-Weighted Citation Impact: 6.55

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Remarkable influence of secondary catalyst site on enantioselective desymmetrization of cyclopentenedione

Authors

Abstract

Topics & Keywords

Publication Details