Valence Tautomeric Transitions with Thermal Hysteresis around Room Temperature and Photoinduced Effects Observed in a Cobalt−Tetraoxolene Complex

2006206 citationsJournal Article

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Abstract

A dinuclear complex, [(CoTPA)2(DHBQ)](PF6)3, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.

Topics & Keywords

Magnetism in coordination complexes Porphyrin and Phthalocyanine Chemistry Metal-Catalyzed Oxygenation Mechanisms

Publication Details

Published in: Journal of the American Chemical Society

Volume 128, Issue 6, pp. 1790-1791

DOI: 10.1021/ja057488u

Field-Weighted Citation Impact: 7.84

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Valence Tautomeric Transitions with Thermal Hysteresis around Room Temperature and Photoinduced Effects Observed in a Cobalt−Tetraoxolene Complex

Authors

Abstract

Topics & Keywords

Publication Details