Highly porous and robust scandium-based metal–organic frameworks for hydrogen storage

2011183 citationsJournal Article

Authors

Ilich A. Ibarra · University of Nottingham

Sihai Yang⧫ · University of Nottingham

Xiang Lin · University of Nottingham

Alexander J. Blake · University of Nottingham

P.J. Rizkallah · Sci-Tech Daresbury

Harriott Nowell · Diamond Light Source

David R. Allan ·

Abstract

The metal-organic frameworks NOTT-400 and NOTT-401, based on a binuclear [Sc(2)(μ(2)-OH)(O(2)CR)(4)] building block, have been synthesised and characterised; the desolvated framework NOTT-401a shows a BET surface area of 1514 m(2) g(-1) with a total H(2) uptake of 4.44 wt% at 77 K and 20 bar.

Topics & Keywords

Metal-Organic Frameworks: Synthesis and Applications Hydrogen Storage and Materials Carbon dioxide utilization in catalysis

Publication Details

Published in: Chemical Communications

Volume 47, Issue 29, pp. 8304-8304

DOI: 10.1039/c1cc11168j

Field-Weighted Citation Impact: 5.38

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Highly porous and robust scandium-based metal–organic frameworks for hydrogen storage

Authors

Abstract

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Publication Details