Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

200922 citationsJournal Article

Authors

Marco Conte · University of York

Yun Ma · University of York

Colin Loyns · Cygnet Hospital Wyke

Peter J. Price · Cygnet Hospital Wyke

David Rippon · Cygnet Hospital Wyke

Victor Chechik · University of York

Abstract

Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.

Topics & Keywords

Oxidative Organic Chemistry Reactions Metal-Catalyzed Oxygenation Mechanisms Catalysis and Oxidation Reactions

Publication Details

Published in: Organic & Biomolecular Chemistry

Volume 7, Issue 13, pp. 2685-2685

DOI: 10.1039/b905893a

Field-Weighted Citation Impact: 0.83

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Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

Authors

Abstract

Topics & Keywords

Publication Details