A Contribution to the Investigation of Enzyme‐Catalysed Hydrolysis of Poly(ethylene terephthalate) Oligomers

Abstract Summary: One strategy to solve the problem of unwanted PET oligomer deposits in textile production is their enzymatic cleavage. In this work a selection of different enzymes (esterases, lipases) were tested for this purpose. The capacity to hydrolyse PET oligomers of some of the tested enzymes has been previously described in the literature. In order to imitate practical conditions both dry and precipitated PET oligomers were used. The decrease in the amount of cyclic trimer, the main component of the PET oligomers, was monitored by HPLC. After treatment with the lipase from Triticum aestivum a decrease of 80 wt.‐% was found. However, the effect of this lipase seems to have less to do with catalysing hydrolytic cleavages of ester groups than with the absorption of the oligomer on the enzyme protein. Cyclic PET trimer ( cyclo ‐tris[ethyleneglycolterephthalate]). magnified image Cyclic PET trimer ( cyclo ‐tris[ethyleneglycolterephthalate]).