High-rate synthesis of Cu–BTC metal–organic frameworks

2013141 citationsJournal Article

Authors

Ki‐Joong Kim · Oregon State University

Yong Jun Li · Oregon State University

Peter B. Kreider · Oregon State University

Chih‐Hung Chang · Oregon State University

Nick Wannenmacher · Oregon State University

Praveen K. Thallapally · Pacific Northwest National Laboratory

Ho‐Geun Ahn

Abstract

The reaction conditions for the synthesis of Cu-BTC (BTC = benzene-1,3,5-tricarboxylic acid) were elucidated using a continuous-flow microreactor-assisted solvothermal system to achieve crystal size and phase control. A high-rate synthesis of Cu-BTC metal-organic frameworks with a BET surface area of more than 1600 m(2) g(-1) (Langmuir surface area of more than 2000 m(2) g(-1)) and with a 97% production yield could be achieved with a total reaction time of 5 minutes.

Topics & Keywords

Metal-Organic Frameworks: Synthesis and Applications Dendrimers and Hyperbranched Polymers Covalent Organic Framework Applications

Publication Details

Published in: Chemical Communications

Volume 49, Issue 98, pp. 11518-11518

DOI: 10.1039/c3cc46049e

Field-Weighted Citation Impact: 3.06

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High-rate synthesis of Cu–BTC metal–organic frameworks

Authors

Abstract

Topics & Keywords

Publication Details