Bonding and Electron Delocalization in Ruthenium(III) σ-Arylacetylide Radicals [trans-Cl(η2-dppe)2RuC≡C(4-C6H4X)]+ (X = NO2, C(O)H, C(O)Me, F, H, OMe, NMe2): Misleading Aspects of the ESR Anisotropy

200970 citationsJournal Article

Authors

N. Gauthier · Institut de Physique de Rennes

Noureddine Tchouar · Institut de Physique de Rennes

Frédéric Justaud · Centre National de la Recherche Scientifique

Gilles Argouarch · Université de Rennes

Marie P. Cifuentes · Institut de Physique de Rennes

Loïc Toupet · Centre National de la Recherche Scientifique

Daniel Touchard

Abstract

The bonding within the series of [trans-Cl(η2-dppe) 2RuC≡C(4-C6H4X)]n+ complexes (1-Xn+; n = 1, 0 and X = NO2, C(O)H, C(O)Me, F, H, OMe, NMe2) has been examined by IR, ESR, and UV-vis-near-IR spectroscopy together with computational modeling. A strong

Topics & Keywords

Magnetism in coordination complexes Organometallic Complex Synthesis and Catalysis Metal complexes synthesis and properties

Publication Details

Published in: Organometallics

Volume 28, Issue 7, pp. 2253-2266

DOI: 10.1021/om801138q

Field-Weighted Citation Impact: 3.56

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Bonding and Electron Delocalization in Ruthenium(III) σ-Arylacetylide Radicals [<i>trans</i>-Cl(η<sup>2</sup>-dppe)<sub>2</sub>RuC≡C(4-C<sub>6</sub>H<sub>4</sub>X)]<sup>+</sup> (X = NO<sub>2</sub>, C(O)H, C(O)Me, F, H, OMe, NMe<sub>2</sub>): Misleading Aspects of the ESR Anisotropy

Authors

Abstract

Topics & Keywords

Publication Details