On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o-R2P(Ph)BR‘2

2006253 citationsJournal Article

Authors

Sébastien Bontemps · Laboratoire de Chimie Théorique

Ghenwa Bouhadir · Université Toulouse III - Paul Sabatier

Karinne Miqueu · Laboratoire Hétérochimie Fondamentale et Appliquée

D. Bourissou · Laboratoire de Chimie Théorique

Abstract

Monophosphine-boranes were shown to behave as bidentate ambiphilic ligands, whose structural versatility has been illustrated by the preparation of PdII and AuI complexes featuring unusual P --> M-Cl --> B and P --> M --> B interactions, respectively.

Topics & Keywords

Organometallic Complex Synthesis and Catalysis Asymmetric Hydrogenation and Catalysis Synthesis and characterization of novel inorganic/organometallic compounds

Publication Details

Published in: Journal of the American Chemical Society

Volume 128, Issue 37, pp. 12056-12057

DOI: 10.1021/ja0637494

Field-Weighted Citation Impact: 13.08

Command Palette

On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands <i>o</i>-R<sub>2</sub>P(Ph)BR‘<sub>2</sub>

Authors

Abstract

Topics & Keywords

Publication Details