Theory of the Thermal Conductivity of Superconductors

A theory of the thermal conductivity of superconductors is presented, based on the theory of superconductivity due to Bardeen, Cooper, and Schrieffer. The excited states of the system are treated as quasi-particles, allowing a Boltzmann equation to be set up. The electronic contribution to the thermal conductivity when the dominant scatterers are impurities has been calculated exactly. The result is very close to that of the Heisenberg-Koppe theory which is in fair agreement with experiment. The variational principle of Wilson has been used to find the electronic conductivity when the dominant scatterers are lattice waves. It is concluded that the theory fails to predict the sharp drop in the ratio $\frac{{\ensuremath{\kappa}}_{\mathrm{es}}}{{\ensuremath{\kappa}}_{\mathrm{en}}}$ as the temperature is lowered below ${T}_{c}$, a feature which is characteristic of the experimental results. The effect of the electrons on the lattice conductivity has also been calculated. The theoretical values may be too large.