Multi-responsive metal–organic lantern cages in solution

201568 citationsJournal Article

Authors

Valentina Brega · Bowling Green State University

Matthias Zeller · St. Elizabeth Youngstown Hospital

Yufan He · Bowling Green State University

H. Peter Lu · Bowling Green State University

Jeremy K. Klosterman · Bowling Green State University

Abstract

Soluble copper-based M4L4 lantern-type metal-organic cages bearing internal amines were synthesized. The solution state integrity of the paramagnetic metal-organic cages was demonstrated using NMR, DLS, MS, and AFM spectroscopy. 1D supramolecular pillars of pre-formed cages or covalent host-guest complexes selectively formed upon treatment with 4,4'-bipyridine and acetic anhydride, respectively.

Topics & Keywords

Supramolecular Chemistry and Complexes Metal-Organic Frameworks: Synthesis and Applications Supramolecular Self-Assembly in Materials

Publication Details

Published in: Chemical Communications

Volume 51, Issue 24, pp. 5077-5080

DOI: 10.1039/c5cc00698h

Field-Weighted Citation Impact: 3.77

Command Palette

Multi-responsive metal–organic lantern cages in solution

Authors

Abstract

Topics & Keywords

Publication Details