Heteropoly-13-Palladates(II) [PdII13(AsVPh)8O32]6− and [PdII13SeIV8O32]6−

200982 citationsJournal Article

Authors

Natalya V. Izarova · Constructor University

Michael H. Dickman · Constructor University

Rosa Ngo Biboum · Centre National de la Recherche Scientifique

Bineta Keita · Centre National de la Recherche Scientifique

Louis Nadjo · Laboratoire de Chimie Physique

V. Ramachandran · Florida State University

Naresh S. Dalal

Abstract

Two discrete anionic palladium(II)-oxo clusters have been prepared: [Pd(13)(As(V)Ph)(8)O(32)](6-) (1) and [Pd(13)Se(IV)(8)O(32)](6-) (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)(2) with PhAsO(3)H(2) and SeO(2) and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry.

Topics & Keywords

Polyoxometalates: Synthesis and Applications Nanocluster Synthesis and Applications Metal-Organic Frameworks: Synthesis and Applications

Publication Details

Published in: Inorganic Chemistry

Volume 48, Issue 16, pp. 7504-7506

DOI: 10.1021/ic900953a

Field-Weighted Citation Impact: 4.84

Command Palette

Heteropoly-13-Palladates(II) [Pd<sup>II</sup><sub>13</sub>(As<sup>V</sup>Ph)<sub>8</sub>O<sub>32</sub>]<sup>6−</sup> and [Pd<sup>II</sup><sub>13</sub>Se<sup>IV</sup><sub>8</sub>O<sub>32</sub>]<sup>6−</sup>

Authors

Abstract

Topics & Keywords

Publication Details