Ternary Hybrids of Amorphous Nickel Hydroxide–Carbon Nanotube‐Conducting Polymer for Supercapacitors with High Energy Density, Excellent Rate Capability, and Long Cycle Life

The utilization of Ni(OH) 2 as a pseudocapacitive material for high performance supercapacitors is hindered by its low electrical conductivity and short cycle life. A coaxial ternary hybrid material comprising of amorphous Ni(OH) 2 deposited on multiwalled carbon nanotubes wrapped with conductive polymer (poly (3,4‐ethylenedioxythiophene)‐poly(styrenesulfonate)) is demonstrated. A thin layer of disordered amorphous Ni(OH) 2 is deposited by an effective “coordinating etching and precipitating” method, resulting in an ultrahigh specific capacitance of 3262 F g −1 at 5 mV s −1 and excellent rate capability (71.9% capacitance retention at 100 mV s −1 ). More importantly, the polymer layer prevents the degradation of the nanostructure and dis­solution of Ni ion during repeated charge–discharge cycling for 30 000 cycles, a phenomenon which often plagues Ni(OH) 2 nanomaterials. Using the ternary Ni(OH) 2 hybrid and the reduced graphene oxide/carbon nanotube hybrid as the positive and negative electrodes, respectively, the assembled asymmetric supercapacitors exhibit high energy density of 58.5 W h kg −1 at the power density of 780 W kg −1 as well as long cycle life (86% capacitance retention after 30 000 cycles). The ternary hybrid architecture design for amorphous Ni(OH) 2 can be regarded as a general approach to obtain pseudocapacitive materials for supercapacitors with both high energy density, excellent rate capability, and long cycle life.