Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity

2015569 citationsJournal Articlehybrid Open Access

Authors

Martin Lammert · Christian-Albrechts-Universität zu Kiel

Michael T. Wharmby · Diamond Light Source

Simon Smolders · Institute of Catalysis and Petrochemistry

Bart Bueken · Institute of Catalysis and Petrochemistry

Alexandra Lieb · University Hospital Magdeburg

Kirill A. Lomachenko · Southern Federal University

Dirk De Vos

Abstract

A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO system was successfully employed for the aerobic oxidation of benzyl alcohol.

Topics & Keywords

Metal-Organic Frameworks: Synthesis and Applications Magnetism in coordination complexes Polyoxometalates: Synthesis and Applications

Publication Details

Published in: Chemical Communications

Volume 51, Issue 63, pp. 12578-12581

DOI: 10.1039/c5cc02606g

Field-Weighted Citation Impact: 8.61

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Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity

Authors

Abstract

Topics & Keywords

Publication Details