Geometric switching of linear to area negative thermal expansion in uniaxial metal–organic frameworks

201470 citationsJournal Articlebronze Open Access

Authors

Matthew G. Tucker · Rutherford Appleton Laboratory

David A. Keen · Rutherford Appleton Laboratory

Andrew L. Goodwin · University of Oxford

Abstract

The direction of anisotropic negative thermal expansion switches for the two quartzlike metal–organic frameworks deuterium indium terephthalate and zinc isonicotinate; we show this inversion to be geometric, rather than chemical, in origin.

Topics & Keywords

Thermal Expansion and Ionic Conductivity Advanced Battery Materials and Technologies Magnesium Oxide Properties and Applications

Publication Details

Published in: CrystEngComm

Volume 16, Issue 17, pp. 3498-3506

DOI: 10.1039/c3ce42165a

Field-Weighted Citation Impact: 4.03

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Geometric switching of linear to area negative thermal expansion in uniaxial metal–organic frameworks

Authors

Abstract

Topics & Keywords

Publication Details