One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation

2015171 citationsJournal Article

Authors

Qihao Yang · Hefei National Center for Physical Sciences at Nanoscale

Yuzhen Chen · Hefei National Center for Physical Sciences at Nanoscale

Qiang Xü · National Institute of Advanced Industrial Science and Technology

Hai‐Long Jiang · Chinese Academy of Sciences

Abstract

The hydrogenation efficiency of nitro compounds was found to be greatly boosted by coupling with dehydrogenation of ammonia borane. The Pd@MIL-101 with tiny Pd NPs is exceptionally efficient and recyclable in the tandem reactions and diverse nitro compounds can be selectively reduced to the corresponding amines in 1.5-5 min with quantitative yields.

Topics & Keywords

Nanomaterials for catalytic reactions Ammonia Synthesis and Nitrogen Reduction Metal-Organic Frameworks: Synthesis and Applications

Publication Details

Published in: Chemical Communications

Volume 51, Issue 52, pp. 10419-10422

DOI: 10.1039/c5cc03102h

Field-Weighted Citation Impact: 12.34

Command Palette

One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation

Authors

Abstract

Topics & Keywords

Publication Details