A New Family of Chiral Binaphthyl‐Derived Cyclophane Receptors: Complexation of Pyranosides

1995147 citationsJournal Article

Authors

Völker Gramlich · Institute of Ethnology

Abstract

Even in the presence of a protic solvent (up to 20% v/v CD3OD) the optically active cyclophane tetraanion in (R,R,R,R)-1 binds to carbohydrates such as 1-O-octyl-β-D-glycopyranoside. In addition, neutral cyclophanes with similarly highly organized cavities are suitable binders in chloroform. The macrocycles are synthesized by Glaser–Hay coupling of novel chiral diethynylated 1,1'-binaphthyl monomers.

Topics & Keywords

Carbohydrate Chemistry and Synthesis Synthesis and Properties of Aromatic Compounds Chemical Synthesis and Analysis

Publication Details

Published in: Angewandte Chemie International Edition in English

Volume 34, Issue 15, pp. 1596-1600

DOI: 10.1002/anie.199515961

Field-Weighted Citation Impact: 8.40

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A New Family of Chiral Binaphthyl‐Derived Cyclophane Receptors: Complexation of Pyranosides

Authors

Abstract

Topics & Keywords

Publication Details