Barium Dibenzopentalenide as a Main‐Group Metal η8 Complex: Facile Synthesis from 1,4‐Dilithio‐1,3‐butadienes and Ba[N(SiMe3)2]2, Structural Characterization, and Reaction Chemistry

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Abstract

Transmetalation of 1,4-dilithio-1,3-butadienes with Ba[N(SiMe3)2]2 gave barium dibenzopentalenides, which were structurally characterized by single-crystal X-ray analysis. A preliminary study of the reaction chemistry of thus obtained barium dibenzopentalenides demonstrated that synthetically useful applications can be expected.

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Coordination Chemistry and Organometallics Organometallic Complex Synthesis and Catalysis Synthesis and characterization of novel inorganic/organometallic compounds

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Published in: Angewandte Chemie International Edition

Volume 52, Issue 41, pp. 10822-10825

DOI: 10.1002/anie.201305254

Field-Weighted Citation Impact: 5.01

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Barium Dibenzopentalenide as a Main‐Group Metal η<sup>8</sup> Complex: Facile Synthesis from 1,4‐Dilithio‐1,3‐butadienes and Ba[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub>, Structural Characterization, and Reaction Chemistry

Authors

Abstract

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Publication Details