Extremely Large Variations of Atmospheric ¹⁴ C Concentration During the Last Glacial Period

A long record of atmospheric 14 C concentration, from 45 to 11 thousand years ago (ka), was obtained from a stalagmite with thermal-ionization mass-spectrometric 230 Th and accelerator mass-spectrometric 14 C measurements. This record reveals highly elevated Δ 14 C between 45 and 33 ka, portions of which may correlate with peaks in cosmogenic 36 Cl and 10 Be isotopes observed in polar ice cores. Superimposed on this broad peak of Δ 14 C are several rapid excursions, the largest of which occurs between 44.3 and 43.3 ka. Between 26 and 11 ka, atmospheric Δ 14 C decreased from ∼700 to ∼100 per mil, modulated by numerous minor excursions. Carbon cycle models suggest that the major features of this record cannot be produced with solar or terrestrial magnetic field modulation alone but also require substantial fluctuations in the carbon cycle.