Formaldehyde in Comets C/1995 O1 (Hale‐Bopp), C/2002 T7 (LINEAR), and C/2001 Q4 (NEAT): Investigating the Cometary Origin of H₂CO

Observations of formaldehyde (H2CO) have been conducted toward comets C/1995 O1 (Hale-Bopp), C/2001 Q4 (NEAT), and C/2002 T7 (LINEAR) using the Arizona Radio Observatory (ARO) 12 m telescope at 1.2 and 2 mm. Aperture synthesis maps of H2CO at 3 mm were made using the Berkeley-Illinois-Maryland Association (BIMA) interferometer toward comet Hale-Bopp. These data indicate that the production rate of H2CO is ~3.7 × 1028 s-1 at ~1 AU in comet Hale-Bopp, using a simple Monte Carlo model, if a nuclear origin for the molecule is assumed. However, maps of H2CO in Hale-Bopp, in comparison with CO, show an extended distribution (rs ~ 15,000 km) with small-scale structure oriented roughly along the comet-Sun direction. This result suggests a source of H2CO other than the comet nucleus. The extended source of formaldehyde is probably grains composed of a mixture of silicates and organic material. The production rate for H2CO increases to Q ~ 1.4 × 1029 s-1 assuming such an extended grain source. This value implies a Q/Q(H2O) ~ 1.4%, which is similar to the production rate ratio of Q/Q(H2O) ~ 4% derived from in situ measurements of H2CO in comet Halley. Production rates for H2CO toward comets C/2002 T7 (LINEAR) and C/2001 Q4 (NEAT) are 1.4 × 1027 and 5.6 × 1026 s-1, respectively, modeled using the extended grain source. The spectra of H2CO measured toward comet C/2002 T7 (LINEAR) show evidence for a second velocity component, most likely arising from comet fragmentation.