Terminal ruthenium carbido complexes as σ-donor ligands

2002100 citationsJournal Article

Authors

Andrew Hejl · California Institute of Technology

Tina M. Trnka · California Institute of Technology

Michael W. Day · California Institute of Technology

Robert H. Grubbs · California Institute of Technology

Abstract

The terminal carbido ligand of (PCy3)2(Cl)2RuC coordinates to other metal centers in a σ-donor fashion, as in (PCy3)2(Cl)2RuC–Pd(Cl)2(SMe2) and (PCy3)2(Cl)2RuC–Mo(CO)5.

Topics & Keywords

Synthetic Organic Chemistry Methods Metal-Catalyzed Oxygenation Mechanisms Organometallic Complex Synthesis and Catalysis

Publication Details

Published in: Chemical Communications

DOI: 10.1039/b207903h

Field-Weighted Citation Impact: 1.74

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Terminal ruthenium carbido complexes as σ-donor ligands

Authors

Abstract

Topics & Keywords

Publication Details