Carbonate Identification and Genesis as Revealed by Staining

ABSTRACT Carbonate minerals are stained over a set period of time with alizarin red-S and potassium ferricyanide only if they will react with dilute hydrochloric acid solution, with which the stain is prepared. The rates of solution of carbonates in the acid control the intensity of color development. For calcite, the rate of solution varies with the optic orientation of the section. The speed of carbonate solution is changed if the acid concentration is altered, but only at concentrations of about 0.1 N is the optic orientation of calcite differentiated by the stain. Etching reduces thin section thickness and clarifies rock texture. Staining with alizarin red-S differentiates carbonate minerals into two groups. Aragonite, calcite, witherite, and cerussite, which dissolve rapidly in dilute hydrochloric acid, are stained, while dolomite, siderite, magnesite, and rhodochosite, which react much more slowly with the acid, remain unstained. The distribution of ferrous iron, as distinguished by staining with potassium ferricyanide, has proved to be highly significant in the genesis of cements. Ferrous iron can be introduced at any one stage in cementation, or repeatedly, forming zoned patterns. The paragenesis of zoned ferroan cements can be reconstructed after staining. Solution of the more soluble original constituents can sometimes be dated in relation to cementation. Ferroan calcite can be secondary in origin and is usually associated with replacement minerals.