Palladium‐Catalyzed Electrophilic Substitution via Monoallylpalladium Intermediates

2003103 citationsJournal Article

Authors

Abstract

Nucleophilic rather than electrophilic reactivity is ascribed to the allyl moiety in (η1-allyl)palladium complexes such as 1, which are generated catalytically from allylstannanes and a palladium pincer complex and react smoothly with aldehydes.

Topics & Keywords

Catalytic Cross-Coupling Reactions Catalytic C–H Functionalization Methods Asymmetric Hydrogenation and Catalysis

UN Sustainable Development Goals

Clean water and sanitation

Publication Details

Published in: Angewandte Chemie International Edition

Volume 42, Issue 31, pp. 3656-3658

DOI: 10.1002/anie.200351477

Field-Weighted Citation Impact: 5.65