Automated Diffraction Tomography for the Structure Elucidation of Twinned, Sub‐micrometer Crystals of a Highly Porous, Catalytically Active Bismuth Metal–Organic Framework

A combined approach: A permanent highly porous bismuth-containing metal–organic framework (CAU-7) has been synthesized and its structure determined by a combination of electron diffraction, Rietveld refinement, and DFT calculations. The compound is catalytically active in the hydroxymethylation of furan (see picture). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.