Gold– and Platinum–Bismuth Donor–Acceptor Interactions Supported by an Ambiphilic PBiP Pincer Ligand

2012105 citationsJournal Article

Authors

Carolin Tschersich · Humboldt-Universität zu Berlin

Christian Limberg · Humboldt-Universität zu Berlin

Stefan Roggan · Humboldt-Universität zu Berlin

Christian Herwig · Humboldt-Universität zu Berlin

N. P. Érnsting · Humboldt-Universität zu Berlin

Sergey A. Kovalenko · Humboldt-Universität zu Berlin

Stefan Mebs

Abstract

Noble metals meet a heavyweight: A pincer ligand brings together bismuth with gold and platinum, so that metallophilic interactions are established. According to DFT calculations, these interactions contain dominant metal→bismuth contributions.

Topics & Keywords

Organometallic Complex Synthesis and Catalysis Asymmetric Hydrogenation and Catalysis Synthesis and characterization of novel inorganic/organometallic compounds

Publication Details

Published in: Angewandte Chemie International Edition

Volume 51, Issue 20, pp. 4989-4992

DOI: 10.1002/anie.201200848

Field-Weighted Citation Impact: 4.49

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Gold– and Platinum–Bismuth Donor–Acceptor Interactions Supported by an Ambiphilic PBiP Pincer Ligand

Authors

Abstract

Topics & Keywords

Publication Details