Polyoxometalate‐Mediated Self‐Assembly of Single‐Molecule Magnets: {[XW9O34]2[MnIII4MnII2O4(H2O)4]}12−

2008268 citationsJournal Article

Authors

Chris Ritchie · University of Glasgow

Alan Ferguson · University of Glasgow

Hiroyuki Nojiri

Haralampos N. Miras · University of Glasgow

Yu‐Fei Song · University of Glasgow

De‐Liang Long · University of Glasgow

E. Burkholder · University of Glasgow

Abstract

Last night of the POMs: The title compound (X=GeIV) exhibits slow relaxation of magnetization and quantum tunneling with a single-molecule magnetic behavior. Significant structural differences in the [MnIII4MnII2O4(H2O)4]8+ cluster core of the X=SiIV analogue modify the magnetic properties, thereby illustrating how polyoxometalate (POM) ligands can help in the systematic construction of nanoscale magnets.

Topics & Keywords

Magnetism in coordination complexes Polyoxometalates: Synthesis and Applications Metal-Organic Frameworks: Synthesis and Applications

Publication Details

Published in: Angewandte Chemie International Edition

Volume 47, Issue 30, pp. 5609-5612

DOI: 10.1002/anie.200801281

Field-Weighted Citation Impact: 10.01

Command Palette

Polyoxometalate‐Mediated Self‐Assembly of Single‐Molecule Magnets: {[XW<sub>9</sub>O<sub>34</sub>]<sub>2</sub>[Mn<sup>III</sup><sub>4</sub>Mn<sup>II</sup><sub>2</sub>O<sub>4</sub>(H<sub>2</sub>O)<sub>4</sub>]}<sup>12−</sup>

Authors

Abstract

Topics & Keywords

Publication Details