Slow Magnetic Relaxation in a Co<sup>II</sup>–Y<sup>III</sup> Single‐Ion Magnet with Positive Axial Zero‐Field Splitting

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Authors

Enrique Colacio · University of Edinburgh

José Ruiz · Universidad de Granada

Eliseo Ruíz · Universitat de Barcelona

E. Cremades · Universitat de Barcelona

J. Krzystek · National High Magnetic Field Laboratory

Stefano Carretta · University of Parma

Joan Cano ·

Abstract

A magnetic Co-production: The complex [Co(μ-L)(μ-OAc)Y(NO3)2] (see structure O red, N blue, C gray), in which the CoII ion exhibits a D value of approximately +45 cm−1, as determined by magnetic and inelastic neutron scattering experiments, exhibits slow magnetic relaxation and single-ion magnet behavior.

Topics & Keywords

Magnetism in coordination complexes Lanthanide and Transition Metal Complexes Advanced NMR Techniques and Applications

Publication Details

Published in: Angewandte Chemie International Edition

Volume 52, Issue 35, pp. 9130-9134

DOI: 10.1002/anie.201304386

Field-Weighted Citation Impact: 11.42

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Slow Magnetic Relaxation in a Co<sup>II</sup>–Y<sup>III</sup> Single‐Ion Magnet with Positive Axial Zero‐Field Splitting

Authors

Abstract

Topics & Keywords

Publication Details