Effects of Co/Sm Composition on the Ordered Phase Formation in Sm-Co Thin Films Grown on Cu(111) Single-Crystal Underlayers

Sm-Co thin films were prepared on Cu(111) single-crystal underlayers by changing the Sm composition from 12 to 35 at.% and the effects of Co/Sm composition on the ordered phase formation were investigated. The epitaxial SmCo <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> thin films were obtained for all samples. The SmCo <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> epitaxial layer grown on Cu underlayer has two different types of domains whose orientations are rotated around film normal by 30 degrees to each other. Cu atoms substitute a part of the Co sites in the SmCo <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> structure, and an alloy compound of Sm(Co,Cu) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> phase was formed for all samples. The Sm(Co,Cu) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> phase was more Cu enriched with increasing the Sm composition. The Cu atom diffusion into Sm-Co layer plays an important role in assisting the formation of Sm(Co,Cu) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> ordered phase.