Modulating single-molecule magnet behaviour of phenoxo-O bridged lanthanide(<scp>iii</scp>) dinuclear complexes by using different β-diketonate coligands

2015153 citationsJournal Article

Authors

Wen‐Min Wang · Tianjin University

Shiyu Wang · Tianjin University

Hongxia Zhang · Tianjin University

Hai-Yun Shen · Tianjin University

Ji‐Yong Zou · Jiangxi Academy of Sciences

Hong‐Ling Gao · Tianjin University

Jian‐Zhong Cui ·

Abstract

Three Dy<sub>2</sub> complexes with similar crystal structure have been synthesized. Magnetic studies reveal that they exhibit different magnetic relaxation behaviors, originating from the different chemical environments of the center Dy<sup>3+</sup> ions with different β-diketonate coligands.

Topics & Keywords

Magnetism in coordination complexes Lanthanide and Transition Metal Complexes Metal-Catalyzed Oxygenation Mechanisms

Publication Details

Published in: Inorganic Chemistry Frontiers

Volume 3, Issue 1, pp. 133-141

DOI: 10.1039/c5qi00192g

Field-Weighted Citation Impact: 6.42

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Modulating single-molecule magnet behaviour of phenoxo-O bridged lanthanide(<scp>iii</scp>) dinuclear complexes by using different β-diketonate coligands

Authors

Abstract

Topics & Keywords

Publication Details