Restricted access to a conical intersection to explain aggregation induced emission in dimethyl tetraphenylsilole

2016178 citationsJournal Article

Authors

Xing‐Liang Peng · Beijing Institute of Technology

Sergi Ruiz‐Barragán · Japan Atomic Energy Agency

Ze‐Sheng Li · Beijing Institute of Technology

Quan‐Song Li · Beijing Institute of Technology

Lluı́s Blancafort · University of Girona

Abstract

Aggregation-induced emission of dimethyl tetraphenylsilole is due to restricted access to a conical intersection. The intersection allows for radiationless decay in solution but is not reachable in the aggregate phase.

Topics & Keywords

Luminescence and Fluorescent Materials Molecular Sensors and Ion Detection Photochemistry and Electron Transfer Studies

UN Sustainable Development Goals

Sustainable cities and communities

Publication Details

Published in: Journal of Materials Chemistry C

Volume 4, Issue 14, pp. 2802-2810

DOI: 10.1039/c5tc03322e

Field-Weighted Citation Impact: 6.81