Proton and ammonia intercalation into layered iron chalcogenides

20186 citationsJournal Article

Authors

Xiuquan Zhou · Park University

Brandon Wilfong · Park University

Sz‐Chian Liou · Park University

Halyna Hodovanets · Park University

Craig M. Brown · National Institute of Standards and Technology

Efrain E. Rodriguez · Park University

Abstract

Structurally related to the iron-based superconductors, two new intercalated iron chalcogenides (H0.5NH3)Fe2Ch2 where Ch = S, Se have been prepared. By topochemical conversion, the protons were exchanged by lithium to form (Li0.5NH3)Fe2Ch2. Hydrogen bonding plays a significant role in the guest-host interactions of these intercalated phases.

Topics & Keywords

Iron-based superconductors research Layered Double Hydroxides Synthesis and Applications Metalloenzymes and iron-sulfur proteins

UN Sustainable Development Goals

Clean water and sanitation

Publication Details

Published in: Chemical Communications

Volume 54, Issue 50, pp. 6895-6898

DOI: 10.1039/c8cc02436g

Field-Weighted Citation Impact: 0.40