The ubiquitous cross-coupling catalyst system ‘Pd(OAc)2’/2PPh3 forms a unique dinuclear PdI complex: an important entry point into catalytically competent cyclic Pd3 clusters

201986 citationsJournal Articlediamond Open Access

Authors

Neil W. J. Scott · University of York

Mark J. Ford · Institute of Crop Science

Christoph Schotes · Dorma (Germany)

Rachel R. Parker · University of York

Adrian C. Whitwood · University of York

Ian J. S. Fairlamb · University of York

Abstract

Pd3-type clusters generated from Pd(OAc)2/<italic>n</italic>PPh3, formed <italic>via</italic> a dinuclear Pd(<sc>i</sc>) species, exhibit high activity in Suzuki–Miyaura cross-coupling.

Topics & Keywords

Catalytic Cross-Coupling Reactions Nanocluster Synthesis and Applications Organometallic Complex Synthesis and Catalysis

Publication Details

Published in: Chemical Science

Volume 10, Issue 34, pp. 7898-7906

DOI: 10.1039/c9sc01847f

Field-Weighted Citation Impact: 4.01

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The ubiquitous cross-coupling catalyst system ‘Pd(OAc)<sub>2</sub>’/2PPh<sub>3</sub> forms a unique dinuclear Pd<sup>I</sup> complex: an important entry point into catalytically competent cyclic Pd<sub>3</sub> clusters

Authors

Abstract

Topics & Keywords

Publication Details