One-step, high-yield synthesis of g-C₃N₄ nanosheets for enhanced visible light photocatalytic activity

A facile template-free one-step synthesis method of ultrathin g-C₃N₄ nanosheets was developed through thermal polycondensation of melamine. The higher temperature, prolonged time and tightly sealed crucible reaction system contributed to the formation of ultrathin g-C₃N₄ nanosheets. The as-synthesized g-C₃N₄ nanosheets were applied to the visible light photocatalytic degradation of RhB. The photocatalytic activity was significantly enhanced with increased calcination temperature from 500 °C to 650 °C and prolonged calcination time from 4 h to 10 h. Interestingly, the obtained ultrathin g-C₃N₄ nanosheets simultaneously possess high yield and excellent photocatalytic activity. Moreover, g-C₃N₄ nanosheets can maintain photochemical stability after five consecutive runs. The remarkably enhanced photocatalytic activity can be interpreted as the synergistic effects of the enhanced crystallinity, the large surface area, the reduced layer thickness and size and the reduced number of defects. A new layer exfoliation and splitting mechanism of the formation of the ultrathin nanosheets was proposed. This work provides a new strategy to develop a facile eco-friendly template-free one-step synthesis method for potential large-scale synthesis of ultrathin nanosheets with high yield, high photocatalytic efficiency and stable activity for environmental and energetic applications.