Inhibiting Solvent Co‐Intercalation in a Graphite Anode by a Localized High‐Concentration Electrolyte in Fast‐Charging Batteries

Lithium-ion batteries with routine carbonate electrolytes cannot exhibit satisfactory fast-charging performance and lithium plating is widely observed at low temperatures. Herein we demonstrate that a localized high-concentration electrolyte consisting of 1.5 M lithium bis(fluorosulfonyl)imide in dimethoxyethane with bis(2,2,2-trifluoroethyl) ether as the diluent, enables fast-charging of working batteries. A uniform and robust solid electrolyte interphase (SEI) can be achieved on graphite surface through the preferential decomposition of anions. The established SEI can significantly inhibit ether solvent co-intercalation into graphite and achieve highly reversible Li⁺ intercalation/de-intercalation. The graphite | Li cells exhibit fast-charging potential (340 mAh g^-1 at 0.2 C and 220 mAh g^-1 at 4 C), excellent cycling stability (ca. 85.5 % initial capacity retention for 200 cycles at 4 C), and impressive low-temperature performance.