From Unavoidable CO₂ Source to CO₂ Sink? A Cement Industry Based on CO₂ Mineralization

The cement industry emits 7% of the global anthropogenic greenhouse gas (GHG) emissions. Reducing the GHG emissions of the cement industry is challenging since cement production stoichiometrically generates CO₂ during calcination of limestone. In this work, we propose a pathway towards a carbon-neutral cement industry using CO₂ mineralization. CO₂ mineralization converts CO₂ into a thermodynamically stable solid and byproducts that can potentially substitute cement. Hence, CO₂ mineralization could reduce the carbon footprint of the cement industry via two mechanisms: (1) capturing and storing CO₂ from the flue gas of the cement plant, and (2) reducing clinker usage by substituting cement. However, CO₂ mineralization also generates GHG emissions due to the energy required for overcoming the slow reaction kinetics. We, therefore, analyze the carbon footprint of the combined CO₂ mineralization and cement production based on life cycle assessment. Our results show that combined CO₂ mineralization and cement production using today's energy mix could reduce the carbon footprint of the cement industry by 44% or even up to 85% considering the theoretical potential. Low-carbon energy or higher blending of mineralization products in cement could enable production of carbon-neutral blended cement. With direct air capture, the blended cement could even become carbon-negative. Thus, our results suggest that developing processes and products for combined CO₂ mineralization and cement production could transform the cement industry from an unavoidable CO₂ source to a CO₂ sink.