Inorganic Metal‐Oxide Photocatalyst for H₂O₂ Production

Hydrogen peroxide (H₂ O₂ ) is a mild but versatile oxidizing agent with extensive applications in bleaching, wastewater purification, medical treatment, and chemical synthesis. The state-of-art H₂ O₂ production via anthraquinone oxidation is hardly considered a cost-efficient and environment-friendly process because it requires high energy input and generates hazardous organic wastes. Photocatalytic H₂ O₂ production is a green, sustainable, and inexpensive process which only needs water and gaseous dioxygen as the raw materials and sunlight as the power source. Inorganic metal oxide semiconductors are good candidates for photocatalytic H₂ O₂ production due to their abundance in nature, biocompatibility, exceptional stability, and low cost. Progress has been made to enhance the photocatalytic activity toward H₂ O₂ production, however, H₂ O₂ photosynthesis is still in the laboratory research phase since the productivity is far from satisfaction. To inspire innovative ideas for boosting the H₂ O₂ yield in photocatalysis, the most well-studied metal oxide photocatalysts are selected and the modification strategies to improve their activity are listed. The mechanisms for H₂ O₂ production over modified photocatalysts are discussed to highlight the facilitating role of the modification methods. Besides, methods for the quantification of H₂ O₂ and associated radical intermediates are provided to guide future studies in this field.