Modified Corn Starch as an Environmentally Friendly Rheology Enhancer and Fluid Loss Reducer for Water-Based Drilling Mud

Summary Drilling fluid rheology and fluid loss property are fundamental parameters that dictate the effectiveness and easiness of a drilling operation. Maintaining these parameters under high temperatures is technically challenging and has been an exciting research area for the drilling industry. Nonetheless, the use of drilling mud additives, particularly synthetic polymers, threaten ecological environments. Herein, modified corn starch (MCS) was synthesized, characterized, and investigated as an environmentally friendly rheology enhancer and filtration loss controlling agent for water-based mud (WBM) at high temperatures. The experimental results indicated that MCS exhibits better performance in improving rheological properties and fluid loss controlling ability for WBM than the commonly used mud additives. With the addition of an optimal concentration (0.3 wt%), MCS improved the rheology and fluid loss behavior of WBM formulation at harsh aging temperature (220°C) by practically 4 times and 1.7 times, respectively. The MCS was revealed to perform superbly over polyanionic cellulose (PAC) addition at all investigated temperatures. The better performance of the MCS was ascribed to the improved entanglements in the mud system owing to the additional hydroxyl (OH) groups. Besides, the Herschel-Bulkley model was found to be a constitutive model that described the rheological properties of the investigated muds satisfactorily. Moreover, the MCS was found to exhibit acceptable biodegradability properties.