Ultrasound assisted synthesis of Fe‐TiO₂ and Ce‐TiO₂ catalysts and subsequent application for photocatalytic, sonocatalytic, and sonophotocatalytic decolorization of basic Victoria blue dye

Abstract Synthesis of Fe‐TiO 2 and Ce‐TiO 2 catalysts using conventional, and ultrasound assisted (US) homogeneous coprecipitation method has been investigated. Effects of ultrasonic irradiation time and ultrasonic power on catalyst synthesis were studied and it was elucidated that best conditions were 140 W and 60 min, respectively. Characterization using FE‐SEM revealed spherical particles with the size range from 36.4 to 49.4 nm whereas XRD analysis affirmed a mixture of anatase, rutile, and brookite TiO 2 phase with crystallite size ranging from 4.18 to 12.99 nm. BET analysis revealed highest specific surface area (211.59 m 2 /g) for the sonochemically synthesized Ce‐TiO 2 . The process intensification benefits demonstrated in catalyst synthesis were better crystallinity, lower particle size, and higher surface area. The application of catalyst efficacy was tested for photocatalytic, sonocatalytic, and sonophotocatalytic oxidation where maximum decolorization as 71.97% was obtained for sonochemically synthesized Ce‐TiO 2 applied in the sonophotocatalytic approach. Studies related to regeneration, stability, and leaching of Ce and Ti ion from the sonochemically synthesized Ce‐TiO 2 catalyst were also performed. It was observed that the catalyst can be regenerated easily and there were no structural changes in the catalyst after regeneration with negligible leaching of the ions from the catalyst into the solution. Overall, an improved process for catalyst synthesis with intensified decolorization application was demonstrated based on the use of ultrasound.